Journal article

Authors list: Schatz, M; Becker, M; Walter, O; Liehr, G; Schindler, S

Publication year: 2001

Pages: 173-179

Journal: Inorganica Chimica Acta

Volume number: 324

Issue number: 1-2

ISSN: 0020-1693

DOI Link: https://doi.org/10.1016/S0020-1693(01)00588-6

Publisher: Elsevier

Abstract: 
The reaction of dioxygen with the copper(I) Bz(3)tren complex (Bz(3)tren = tris(2-benzylaminoethyl)anline) complex has been investigated using low temperature stopped-flow techniques, The formation of a superoxo as well as a peroxo complex as intermediates was detected spectroscopically. The copper(II) complexes [Cu(Bz(3)tren)H2O](ClO4)(2) and [Cu(Bz(3)tren)Cl]Cl were synthesized and structurally characterized. Both complexes react with dioxygen in solution and formation of benzaldehyde was observed. (C) 2001 Elsevier Science B.V. All rights reserved.

Harvard Citation style: Schatz, M., Becker, M., Walter, O., Liehr, G. and Schindler, S. (2001) Reactivity towards dioxygen of a copper(I) complex of tris(2-benzylaminoethyl)amine, Inorganica Chimica Acta, 324(1-2), pp. 173-179. https://doi.org/10.1016/S0020-1693(01)00588-6

APA Citation style: Schatz, M., Becker, M., Walter, O., Liehr, G., & Schindler, S. (2001). Reactivity towards dioxygen of a copper(I) complex of tris(2-benzylaminoethyl)amine. Inorganica Chimica Acta. 324(1-2), 173-179. https://doi.org/10.1016/S0020-1693(01)00588-6