Journalartikel

Oligoindenopyrenes: A new class of polycyclic aromatics


AutorenlisteWegner, HA; Reisch, H; Rauch, K; Demeter, A; Zachariasse, KA; de Meijere, A; Scott, LT

Jahr der Veröffentlichung2006

Seiten9080-9087

ZeitschriftThe Journal of Organic Chemistry

Bandnummer71

Heftnummer24

ISSN0022-3263

DOI Linkhttps://doi.org/10.1021/jo0613939

VerlagAmerican Chemical Society


Abstract
A new class of polycyclic aromatic hydrocarbons-oligoindenopyrenes-has been synthesized featuring a Pd-catalyzed Suzuki-Heck coupling cascade. The oligoindenopyrenes are robust, highly colored substructures of C-70 and have properties that might prove useful in new organic materials or devices. After excitation, the tetraindenopyrene derivative 3d undergoes efficient deactivation ( 99%) by internal conversion to the ground state. The small fluorescence quantum yield ( 0.004) is in accordance with the short ( 0.6 ns) fluorescence decay time.



Zitierstile

Harvard-ZitierstilWegner, H., Reisch, H., Rauch, K., Demeter, A., Zachariasse, K., de Meijere, A., et al. (2006) Oligoindenopyrenes: A new class of polycyclic aromatics, The Journal of Organic Chemistry, 71(24), pp. 9080-9087. https://doi.org/10.1021/jo0613939

APA-ZitierstilWegner, H., Reisch, H., Rauch, K., Demeter, A., Zachariasse, K., de Meijere, A., & Scott, L. (2006). Oligoindenopyrenes: A new class of polycyclic aromatics. The Journal of Organic Chemistry. 71(24), 9080-9087. https://doi.org/10.1021/jo0613939


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