Journalartikel

Autorenliste: Würtele, C; Gaoutchenova, E; Harms, K; Holthausen, MC; Sundermeyer, J; Schindler, S

Jahr der Veröffentlichung: 2006

Seiten: 3867-3869

Zeitschrift: Angewandte Chemie International Edition

Bandnummer: 45

Heftnummer: 23

ISSN: 1433-7851

Open Access Status: Bronze

DOI Link: https://doi.org/10.1002/anie.200600351

Verlag: Wiley

Abstract: 

No doubt: The high‐quality crystal structure of [Cu(TMG₃tren)(O₂)]SbF₆
(see picture) presents the first unambiguous characterization of a
bioinorganic compound in which a dioxygen molecule coordinates end‐on to
a Cu^I ion. This species, which is best described as a
superoxo copper(II) complex, serves as a model complex for initially
formed Cu–O₂ adducts present in a variety of active sites of copper enzymes.

Harvard-Zitierstil: Würtele, C., Gaoutchenova, E., Harms, K., Holthausen, M., Sundermeyer, J. and Schindler, S. (2006) Crystallographic characterization of a synthetic 1:1 end-on copper dioxygen adduct complex, Angewandte Chemie International Edition, 45(23), pp. 3867-3869. https://doi.org/10.1002/anie.200600351

APA-Zitierstil: Würtele, C., Gaoutchenova, E., Harms, K., Holthausen, M., Sundermeyer, J., & Schindler, S. (2006). Crystallographic characterization of a synthetic 1:1 end-on copper dioxygen adduct complex. Angewandte Chemie International Edition. 45(23), 3867-3869. https://doi.org/10.1002/anie.200600351