Journalartikel

Autorenliste: Alexopoulou, KI; Leibold, M; Walter, O; Zevaco, TA; Schindler, S

Jahr der Veröffentlichung: 2017

Seiten: 4722-4732

Zeitschrift: European Journal of Inorganic Chemistry

Bandnummer: 2017

Heftnummer: 40

ISSN: 1434-1948

DOI Link: https://doi.org/10.1002/ejic.201700854

Verlag: Wiley-VCH Verlag

Abstract: 
Nickel(II) complexes of a series of tripodal ligands (and derivatives), for example, [Ni(Me(6)tren)(DMF)](ClO4)(2) [Me(6)tren = tris(2-dimethylaminoethyl)-amine], are prepared and structurally characterized. The complexes are tested for their potential to be used as mediators for electroreductive coupling of butadiene and carbon dioxide. From the whole series, the complex [Ni(Me(5)dien)(DMF)(3)](ClO4)(2) (Me(5)dien = 1,1,4,7,7-pentamethyl-diethylenetriamine) yields the highest amount of 3 hexene-1,6 diacid (HDS), thus leading to the same result as the best nickel complex (with the ligand 2,4,4-trimethyl-1,5,9-triazacyclodecan, N3) so far reported in the literature.

Harvard-Zitierstil: Alexopoulou, K., Leibold, M., Walter, O., Zevaco, T. and Schindler, S. (2017) Synthesis and Characterization of a Series of Nickel Complexes with Tripodal and Related Ligands: Electroreductive Coupling of Alkynes and Carbon Dioxide, European Journal of Inorganic Chemistry, 2017(40), pp. 4722-4732. https://doi.org/10.1002/ejic.201700854

APA-Zitierstil: Alexopoulou, K., Leibold, M., Walter, O., Zevaco, T., & Schindler, S. (2017). Synthesis and Characterization of a Series of Nickel Complexes with Tripodal and Related Ligands: Electroreductive Coupling of Alkynes and Carbon Dioxide. European Journal of Inorganic Chemistry. 2017(40), 4722-4732. https://doi.org/10.1002/ejic.201700854