Journal article

A rational chemical synthesis of C-60


Authors listScott, LT; Boorum, MM; McMahon, BJ; Hagen, S; Mack, J; Blank, J; Wegner, H; de Meijere, A

Publication year2002

Pages1500-1503

JournalScience

Volume number295

Issue number5559

ISSN0036-8075

DOI Linkhttps://doi.org/10.1126/science.1068427

PublisherAmerican Association for the Advancement of Science


Abstract
Notable quantities of C-60, the smallest stable fullerene, have been synthesized in 12 steps from commercially available starting materials by rational chemical methods. A molecular polycyclic aromatic precursor bearing chlorine substituents at key positions forms C-60 when subjected to flash vacuum pyrolysis at 1100degreesC. No other fullerenes are formed as by-products. The methods we have developed for the target-specific synthesis of fullerenes, applied here to a synthesis of C-60, should make possible the directed laboratory preparation of other fullerenes as well, including those not accessible by graphite vaporization.



Citation Styles

Harvard Citation styleScott, L., Boorum, M., McMahon, B., Hagen, S., Mack, J., Blank, J., et al. (2002) A rational chemical synthesis of C-60, Science, 295(5559), pp. 1500-1503. https://doi.org/10.1126/science.1068427

APA Citation styleScott, L., Boorum, M., McMahon, B., Hagen, S., Mack, J., Blank, J., Wegner, H., & de Meijere, A. (2002). A rational chemical synthesis of C-60. Science. 295(5559), 1500-1503. https://doi.org/10.1126/science.1068427


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