Journal article

Synthesis and Property Studies of Cyclotrisazobenzenes


Authors listReuter, R; Hostettler, N; Neuburger, M; Wegner, HA

Publication year2009

Pages5647-5652

JournalEuropean Journal of Organic Chemistry

Volume number2009

Issue number32

ISSN1434-193X

DOI Linkhttps://doi.org/10.1002/ejoc.200900861

PublisherWiley


Abstract
Azobenzenophanes are fascinating macrocycles, which are of special interest due to their unique photochromic behavior. Cyclotrisazobenzenes 2 (R = H, Br, tBu) were prepared to probe how much strain the photoisomerization of the azobenzene motive can tolerate. The macrocycles were synthesized in an overall yield of 10-20% from ortho-phenylenediamine (6). Solid-state structures of cyclotrisazobenzenes 2a and 2b were obtained. Irradiation under various conditions did not induce any isomerization.



Citation Styles

Harvard Citation styleReuter, R., Hostettler, N., Neuburger, M. and Wegner, H. (2009) Synthesis and Property Studies of Cyclotrisazobenzenes, European Journal of Organic Chemistry, 2009(32), pp. 5647-5652. https://doi.org/10.1002/ejoc.200900861

APA Citation styleReuter, R., Hostettler, N., Neuburger, M., & Wegner, H. (2009). Synthesis and Property Studies of Cyclotrisazobenzenes. European Journal of Organic Chemistry. 2009(32), 5647-5652. https://doi.org/10.1002/ejoc.200900861


Last updated on 2025-21-05 at 15:11