Syntheses, Structures and Properties of Copper(I) and Copper(II) Complexes of the Ligand N,N′‐Bis[2′‐(dimethylamino)ethyl]‐N,N′‐dimethylethane1,2‐diamine (Me6trien)
Authors list: Becker, M; Heinemann, FW; Knoch, F; Donaubauer, W; Liehr, G; Schindler, S; Golub, G; Cohen, H; Meyerstein, D
Abstract: Copper(I) and copper(II) complexes of the ligand N,N'-bis[2'-(dimethylamino)ethyl]-N,N'-dimethylethane-1,2-diamine (Me(6)trien) were synthesized and structurally characterized. In the solid state the complex cation [Cu(Me(6)trien)](+) (1) adopts a distorted tetrahedral configuration, Crystallography, EPR measurements, and UV/Vis spectroscopy indicate that the analogous copper(II) complex [Cu(Me(6)trien)Cl](+) has a square pyramidal geometry in the solid state as well as in solution. The reaction of 1 with dioxygen was investigated in different solvents. No copper dioxygen intermediates could be detected spectrophotometrically during these reactions.
Harvard Citation style: Becker, M., Heinemann, F., Knoch, F., Donaubauer, W., Liehr, G., Schindler, S., et al. (2000) Syntheses, Structures and Properties of Copper(I) and Copper(II) Complexes of the Ligand N,N′‐Bis[2′‐(dimethylamino)ethyl]‐N,N′‐dimethylethane1,2‐diamine (Me6trien), European Journal of Inorganic Chemistry, 2000(4), pp. 719-726. https://doi.org/10.1002/(SICI)1099-0682(200004)2000:4<719::AID-EJIC719>3.0.CO;2-N
APA Citation style: Becker, M., Heinemann, F., Knoch, F., Donaubauer, W., Liehr, G., Schindler, S., Golub, G., Cohen, H., & Meyerstein, D. (2000). Syntheses, Structures and Properties of Copper(I) and Copper(II) Complexes of the Ligand N,N′‐Bis[2′‐(dimethylamino)ethyl]‐N,N′‐dimethylethane1,2‐diamine (Me6trien). European Journal of Inorganic Chemistry. 2000(4), 719-726. https://doi.org/10.1002/(SICI)1099-0682(200004)2000:4<719::AID-EJIC719>3.0.CO;2-N
