Journalartikel

Autorenliste: Schatz, M; Raab, V; Foxon, SP; Brehm, G; Schneider, S; Reiher, M; Holthausen, MC; Sundermeyer, J; Schindler, S

Jahr der Veröffentlichung: 2004

Seiten: 4360-4363

Zeitschrift: Angewandte Chemie International Edition

Bandnummer: 43

Heftnummer: 33

ISSN: 1433-7851

DOI Link: https://doi.org/10.1002/anie.200454125

Verlag: Wiley

Abstract: 

A tale of two modes: An end‐on copper superoxo complex was identified in a combined experimental and theoretical study. Theory clearly discloses the presence of an end‐on complex (see picture, O red, Cu pink, N green) with a minute isotopic resonance Raman splitting below experimental resolution. The results cast doubts on the uncritical use of ¹⁶O,¹⁸O isotopic‐labeling Raman experiments to discriminate end‐on from side‐on bonding modes in M(O₂) complexes.

Harvard-Zitierstil: Schatz, M., Raab, V., Foxon, S., Brehm, G., Schneider, S., Reiher, M., et al. (2004) Combined spectroscopic and theoretical evidence for a persistent end-on copper superoxo complex, Angewandte Chemie International Edition, 43(33), pp. 4360-4363. https://doi.org/10.1002/anie.200454125

APA-Zitierstil: Schatz, M., Raab, V., Foxon, S., Brehm, G., Schneider, S., Reiher, M., Holthausen, M., Sundermeyer, J., & Schindler, S. (2004). Combined spectroscopic and theoretical evidence for a persistent end-on copper superoxo complex. Angewandte Chemie International Edition. 43(33), 4360-4363. https://doi.org/10.1002/anie.200454125