Synthesis and characterization of a new dinuclear bis(mu-oxo)manganese(III)/manganese(IV) complex - Research portal of Justus Liebig University Giessen:

Journal article

Synthesis and characterization of a new dinuclear bis(mu-oxo)manganese(III)/manganese(IV) complex

Authors list: Schindler, S; Walter, O; Pedersen, JZ; Toftlund, H

Publication year: 2000

Pages: 215-219

Journal: Inorganica Chimica Acta

Volume number: 303

Issue number: 2

ISSN: 0020-1693

DOI Link: https://doi.org/10.1016/S0020-1693(00)00036-0

Publisher: Elsevier

Abstract:
[(pmap)Mn-(mu-O)(2)-Mn(pmap)](ClO4)(3), a dinuclear bis(mu-oxo)manganese (III, IV) complex, was synthesized by the reaction of Mn(ClO4)(2) with bis[2-(2-pyridyl)ethyl]-2-pyridylmethyl (= pmap) and hydrogen peroxide. The complex was characterized structurally and EPR-measurements showed the characteristic 16 line signal for a bis-(mu-oxo)Mn(III)/Mn(IV) dimer. The corresponding complex with tris[2-(2-pyridyl)ethyl]amine (= tepa) could not be synthesized; it is most likely that in this complex, the Mn-Mn separation would be too long for a bis(mu-oxo) bridge. (C) 2000 Elsevier Science S.A. All rights reserved.

Authors/Editors

- Uni.-Prof. Dr. Siegfried Adolf Schindler

Citation Styles

Harvard Citation style: Schindler, S., Walter, O., Pedersen, J. and Toftlund, H. (2000) Synthesis and characterization of a new dinuclear bis(mu-oxo)manganese(III)/manganese(IV) complex, Inorganica Chimica Acta, 303(2), pp. 215-219. https://doi.org/10.1016/S0020-1693(00)00036-0

APA Citation style: Schindler, S., Walter, O., Pedersen, J., & Toftlund, H. (2000). Synthesis and characterization of a new dinuclear bis(mu-oxo)manganese(III)/manganese(IV) complex. Inorganica Chimica Acta. 303(2), 215-219. https://doi.org/10.1016/S0020-1693(00)00036-0