Journal article

Coulometric titration at low temperatures - nonstoichiometric silver selenide


Authors listBeck, G; Janek, J

Publication year2004

Pages129-133

JournalSolid State Ionics

Volume number170

Issue number1-2

ISSN0167-2738

DOI Linkhttps://doi.org/10.1016/j.ssi.2004.02.024

PublisherElsevier


Abstract
A modified coulometric titration technique is described for the investigation of nonstoichiometric phases at low temperatures. It allows to obtain titration curves at temperatures where the conventional coulometric titration technique fails because of too small chemical diffusion coefficients of the mobile component. This method for indirect coulometric titration is applied to silver selenide between - 100 and 100 degreesC. The titration curves are analyzed on the basis of a defect chemical model and provide thermodynamic data of the alpha-silver selenide phase. The boundaries of the homogeneous phase field are determined.



Citation Styles

Harvard Citation styleBeck, G. and Janek, J. (2004) Coulometric titration at low temperatures - nonstoichiometric silver selenide, Solid State Ionics, 170(1-2), pp. 129-133. https://doi.org/10.1016/j.ssi.2004.02.024

APA Citation styleBeck, G., & Janek, J. (2004). Coulometric titration at low temperatures - nonstoichiometric silver selenide. Solid State Ionics. 170(1-2), 129-133. https://doi.org/10.1016/j.ssi.2004.02.024


Last updated on 2025-21-05 at 15:31