Journal article

Authors list: Zottnick, SH; Sorg, JR; Sprenger, JAP; Finze, M; Müller-Buschbaum, K

Publication year: 2015

Pages: 164-167

Journal: Journal of Inorganic and General Chemistry

Volume number: 641

Issue number: 2

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.201400498

Publisher: Wiley

Abstract: 
A coordination polymer of the formula 1∞[Pr(BSB)3(py)2] constituted of bis(salicylato)borate anions ([BSB]–) and Pr3+ was synthesized as single crystals from the sodium salt under solvothermal conditions in pyridine. The formation of sodium chloride is a driving force valid for a reaction under solvothermal and ionothermal conditions using the ionic liquid (IL) 1‐ethyl‐3‐methylimidazolium‐bis(salicylato)borate [EMIM][BSB]. For the formation of isoconstitutional compounds the latter reaction also requires a certain amount of pyridine, which is beneficial for crystallization. In addition, a different precursor has to be employed: whilst the solvothermal reaction can be carried out with the anhydrous halide LnCl3, the IL‐based reaction is only successful with the complex [LnCl3(py)4] as precursor.

Harvard Citation style: Zottnick, S., Sorg, J., Sprenger, J., Finze, M. and Müller-Buschbaum, K. (2015) 1∞[Pr(BSB)3(py)2]: A Lanthanide Bis(salicylato)borate at the Junction between Solvothermal and Ionothermal Conditions, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 641(2), pp. 164-167. https://doi.org/10.1002/zaac.201400498

APA Citation style: Zottnick, S., Sorg, J., Sprenger, J., Finze, M., & Müller-Buschbaum, K. (2015). 1∞[Pr(BSB)3(py)2]: A Lanthanide Bis(salicylato)borate at the Junction between Solvothermal and Ionothermal Conditions. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 641(2), 164-167. https://doi.org/10.1002/zaac.201400498