Journalartikel

Autorenliste: Quitmann, CC; Müller-Buschbaum, K

Jahr der Veröffentlichung: 2004

Seiten: 5994-5996

Zeitschrift: Angewandte Chemie International Edition

Bandnummer: 43

Heftnummer: 44

ISSN: 1433-7851

DOI Link: https://doi.org/10.1002/anie.200460478

Verlag: Wiley

Abstract: 

Centered by a nitride ion: The oxidation of ytterbium with 2,2′‐dipyridylamine in liquid ammonia at low temperatures leads to the novel compound [Yb3N(dpa)6][Yb(dpa)3], which is unique among homoleptic dipyridylamides of the rare‐earth metals. The complete deprotonation of NH3 provides the first molecular nitride of a rare‐earth metal with a Yb3N unit (see picture; C blue, N green, Yb silver).

Harvard-Zitierstil: Quitmann, C. and Müller-Buschbaum, K. (2004) [Yb3N(dpa)(6)][Yb(dpa)(3)]: A molecular nitride of a rare-earth metal with a Yb3N unit, Angewandte Chemie International Edition, 43(44), pp. 5994-5996. https://doi.org/10.1002/anie.200460478

APA-Zitierstil: Quitmann, C., & Müller-Buschbaum, K. (2004). [Yb3N(dpa)(6)][Yb(dpa)(3)]: A molecular nitride of a rare-earth metal with a Yb3N unit. Angewandte Chemie International Edition. 43(44), 5994-5996. https://doi.org/10.1002/anie.200460478