Journal article

Authors list: Quitmann, CC; Müller-Buschbaum, K

Publication year: 2005

Pages: 2651-2654

Journal: Journal of Inorganic and General Chemistry

Volume number: 631

Issue number: 13-14

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.200500090

Publisher: Wiley

Abstract: 
The compounds [Ln(Pyr)(3)(BiPY)(2)], Ln = Pr (1), Yb (2), (Pyr(-) = pyrrolate anion, C4H4N-; Bipy = 2,2'-bipyridyl, C10H8N2) were obtained by the solvothermal reaction of pyrrole with praseodymium and ytterbium metal and the amine bipyridine. Yellow-green single crystals of I and yellow crystals of 2 are formed next to dark green solutions. 1 and 2 are isotypic and exhibit monomeric molecules with a complete nitrogen coordination of three pyrrolate anions and two bipyridine molecules around the trivalent rare earth ions. Thus co-coordination with Bipy renders unsubstituted pyrrolates of the rare earth elements feasible from solvothermal conditions in addition to previous low-temperature syntheses. The products were investigated by X-ray single crystal diffraction, Mid IR and Far IR spectroscopy.

Harvard Citation style: Quitmann, C. and Müller-Buschbaum, K. (2005) Complete Nitrogen Coordination in Rare Earth Bipyridine Pyrrolate Complexes from Pyrrole under Solvothermal Conditions: [Ln(Pyr)3(Bipy)2], Ln = Pr, Yb, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 631(13-14), pp. 2651-2654. https://doi.org/10.1002/zaac.200500090

APA Citation style: Quitmann, C., & Müller-Buschbaum, K. (2005). Complete Nitrogen Coordination in Rare Earth Bipyridine Pyrrolate Complexes from Pyrrole under Solvothermal Conditions: [Ln(Pyr)3(Bipy)2], Ln = Pr, Yb. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 631(13-14), 2651-2654. https://doi.org/10.1002/zaac.200500090