Journal article

Authors list: Zottnick, SH; Seuffert, MT; Kerpen, C; Finze, M; Müller-Buschbaum, K

Publication year: 2017

Pages: 4668-4672

Journal: European Journal of Inorganic Chemistry

Volume number: 2017

Issue number: 38-39

ISSN: 1434-1948

DOI Link: https://doi.org/10.1002/ejic.201700547

Publisher: Wiley-VCH Verlag

Abstract: 
The first lanthanide tricyanohydridoborates have been synthesized from anhydrous lanthanide chlorides and the oxonium salt (H3O)[BH(CN)(3)]. Thereby, the three-dimensional, homoleptic coordination polymers (3)[Ln{BH(CN)(3)}(3)] (Ln = Eu, Tb) could be obtained in solvothermal reactions upon complete substitution of the chloride anions by [BH(CN)(3)](-) anions. Both products exhibit intense and characteristic photoluminescence in the visible region through lanthanide-specific 4f-4f transitions with long luminescence decay times typical for the respective lanthanide ions. [BH(CN)(3)](-) proves to be a suitable linker for new lanthanide coordination polymers.

Harvard Citation style: Zottnick, S., Seuffert, M., Kerpen, C., Finze, M. and Müller-Buschbaum, K. (2017) Homoleptic Luminescent Lanthanide Frameworks with the Tricyanohydridoborate Anion, European Journal of Inorganic Chemistry, 2017(38-39), pp. 4668-4672. https://doi.org/10.1002/ejic.201700547

APA Citation style: Zottnick, S., Seuffert, M., Kerpen, C., Finze, M., & Müller-Buschbaum, K. (2017). Homoleptic Luminescent Lanthanide Frameworks with the Tricyanohydridoborate Anion. European Journal of Inorganic Chemistry. 2017(38-39), 4668-4672. https://doi.org/10.1002/ejic.201700547