Journal article

Authors list: Sorg, JR; Oberst, KC; Müller-Buschbaum, K

Publication year: 2018

Pages: 1293-1296

Journal: Journal of Inorganic and General Chemistry

Volume number: 644

Issue number: 21

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.201800257

Publisher: Wiley

Abstract: 
We present the synthesis of the three-dimensional coordination polymer (3)(infinity)[Bi2Br6(tcpt)] [tcpt = 1,3,5-tris(4-cyanophenyl)triazine] that could be obtained from a solvent-free melt synthesis of BiBr3 and 1,4-dicyanobenzene (dcb). The reaction is based on a quantitative in-situ formation of the ligand 1,3,5-tris(4-cyanophenyl)triazine by trimerization of the dicyanobenzene, and, to the best of our knowledge, is the first Bi-containing coordination polymer constructed from Bi-nitrile bonds. The framework further exhibits some pi stacking of the tcpt ligands. (3)(infinity)[Bi2Br6(tcpt)] exhibits green photoluminescence arising from broad banded excitation and emission bands. Furthermore, a photochromic shift of the emission can be observed depending on the excitation wavelength.

Harvard Citation style: Sorg, J., Oberst, K. and Müller-Buschbaum, K. (2018) In-situ Ligand Formation Based Synthesis of a Luminescent Bi-Nitrile Based Framework: (3)(infinity)[Bi2Br6(tcpt)], Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 644(21), pp. 1293-1296. https://doi.org/10.1002/zaac.201800257

APA Citation style: Sorg, J., Oberst, K., & Müller-Buschbaum, K. (2018). In-situ Ligand Formation Based Synthesis of a Luminescent Bi-Nitrile Based Framework: (3)(infinity)[Bi2Br6(tcpt)]. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 644(21), 1293-1296. https://doi.org/10.1002/zaac.201800257