Journal article

Authors list: Dannenbauer, N; Zottnick, SH; Müller-Buschbaum, K

Publication year: 2017

Pages: 1991-1996

Journal: Journal of Inorganic and General Chemistry

Volume number: 643

Issue number: 23

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.201700273

Publisher: Wiley

Abstract: 
In order to evaluate the structural and spectroscopic influence of further pyridyl ligands, e.g. as sensitizers for Ln(3+)-based photoluminescence, the ligand trans-1-(2-pyridyl)-2-(pyridyl)ethylene (tppe) was selected. In reactions with trivalent chlorides of the lanthanides and thiazole (thz), complexes of the formula [LnCl(3)(tppe)(2)(thz)(2)] were obtained for Ln = Nd, Tb, Ho, Er. They are isotypic along the series of the lanthanides and provide ligand sensitizer functions for the Ln-luminescence emission of Nd3+ and Er3+ in the near infrared region. Alike 1,2-bis(4-pyridyl)ethylene, no sensitization is observed for the 4f-based emission of Tb3+ in the visible.

Harvard Citation style: Dannenbauer, N., Zottnick, S. and Müller-Buschbaum, K. (2017) Sensitization of NIR Photoluminescence of Lanthanides in [LnCl(3)(tppe)(2)(thz)(2)] by trans-1-(2-pyridyl)-2-(pyridyl)ethylene, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 643(23), pp. 1991-1996. https://doi.org/10.1002/zaac.201700273

APA Citation style: Dannenbauer, N., Zottnick, S., & Müller-Buschbaum, K. (2017). Sensitization of NIR Photoluminescence of Lanthanides in [LnCl(3)(tppe)(2)(thz)(2)] by trans-1-(2-pyridyl)-2-(pyridyl)ethylene. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 643(23), 1991-1996. https://doi.org/10.1002/zaac.201700273