Journalartikel

Autorenliste: Falk, F; Herkert, L; Hackbarth, L; Müller-Buschbaum, K; Finze, M; Köckerling, M

Jahr der Veröffentlichung: 2017

Seiten: 625-630

Zeitschrift: Journal of Inorganic and General Chemistry

Bandnummer: 643

Heftnummer: 9

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.201700040

Verlag: Wiley

Abstract: 
Six new rare-earth metal tetracyanidoborates were prepared and characterized by single-crystal X-ray diffraction. Crystals of these salts contain co-crystallized solvent molecules, such as water, acetone, ethanol, or diethyl ether. In [La(EtOH)(3)(H2O)(2){B(CN)(4)}(3)] (1), [La-(EtOH)(H2O)(4){B(CN)(4)}(3)]Et2O (2), and [Y(EtOH)(H2O)(4){B(CN)(4)}(3)]EtOH (6) the tetracyanidoborate anions are all or in part bonded to the RE3+ ions, whereas in [Pr(H2O)(9)][B(CN)(4)](3)(CH3)(2)CO (3), [Er(H2O)(8)]-[B(CN)(4)](3)(CH3)(2)CO (4), and [Lu(EtOH)(H2O)(7)][B(CN)(4)](3)EtOH0.5H(2)O (5) the [B(CN)(4)](-) anions are not coordinated to the central metal atoms. Only in 1, one of the three crystallographically independent [B(CN)(4)](-) anions acts as a bridging ligand.

Harvard-Zitierstil: Falk, F., Herkert, L., Hackbarth, L., Müller-Buschbaum, K., Finze, M. and Köckerling, M. (2017) Syntheses and Structures of New Rare-Earth Metal Tetracyanidoborates, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 643(9), pp. 625-630. https://doi.org/10.1002/zaac.201700040

APA-Zitierstil: Falk, F., Herkert, L., Hackbarth, L., Müller-Buschbaum, K., Finze, M., & Köckerling, M. (2017). Syntheses and Structures of New Rare-Earth Metal Tetracyanidoborates. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 643(9), 625-630. https://doi.org/10.1002/zaac.201700040