Journal article

Thiazole and the Diazines Pyrazine and Pyrimidine as Sensitizers for Lanthanide Luminescence from VIS to NIR


Authors listDannenbauer, N; Zottnick, SH; Müller-Buschbaum, K

Publication year2017

Pages1513-1518

JournalJournal of Inorganic and General Chemistry

Volume number643

Issue number21

ISSN0044-2313

DOI Linkhttps://doi.org/10.1002/zaac.201700232

PublisherWiley


Abstract
Complexes and coordination polymers were obtained from trivalent lanthanide chlorides together with thiazole (thz) and the diazine ligands pyrazine (pyz) and pyrimidine (pym). The compounds [Ln(2)Cl(6)(pyz)(thz)(6)]center dot 2thz (Ln = Tb, Er), (1)(infinity)[Pr2Cl6(pyz)(thz)(6)], and [Ln(2)Cl(6)(pym)(2)(thz)(4)] (Ln = Tb, Er) could be obtained, their crystal structures, luminescence as well as thermal properties were determined. The compounds with Tb and Er show intense luminescence with a strong sensitizer effect of the ligands that can be observed by dominant ligand excitation and exclusive metal emission for VIS and NIR.



Citation Styles

Harvard Citation styleDannenbauer, N., Zottnick, S. and Müller-Buschbaum, K. (2017) Thiazole and the Diazines Pyrazine and Pyrimidine as Sensitizers for Lanthanide Luminescence from VIS to NIR, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 643(21), pp. 1513-1518. https://doi.org/10.1002/zaac.201700232

APA Citation styleDannenbauer, N., Zottnick, S., & Müller-Buschbaum, K. (2017). Thiazole and the Diazines Pyrazine and Pyrimidine as Sensitizers for Lanthanide Luminescence from VIS to NIR. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 643(21), 1513-1518. https://doi.org/10.1002/zaac.201700232


Last updated on 2025-21-05 at 15:49