Journalartikel

Autorenliste: Kraft, A; Roth, P; Schmidt, D; Stangl, J; Müller-Buschbaum, K; Beuerle, F

Jahr der Veröffentlichung: 2016

Seiten: 5982-5987

Zeitschrift: Chemistry - A European Journal

Bandnummer: 22

Heftnummer: 17

ISSN: 0947-6539

DOI Link: https://doi.org/10.1002/chem.201505137

Verlag: Wiley

Abstract: 
Hexakis-substituted [60]fullerene adducts with icosahedral symmetry provide an unprecedented scaffold for the spatial arrangement of twelve functional groups with high geometric precision. This unique molecular symmetry identifies such polyfunctional organic building blocks as potential highly connective linkers for coordination polymer and metal-organic framework synthesis. Hereby, the linker exhibits a higher connectivity than the metal ions and with the main connectivity based on the ligand, this can create a new type of inversely cross-linked framework. Two hexakis adducts bearing either twelve glycolic acid or 3-hydroxypropionic acid side chains attached to its malonate units were incorporated as organic connectivity centers in the first fullerene-containing three-dimensional frameworks by coordination with Zn2+.

Harvard-Zitierstil: Kraft, A., Roth, P., Schmidt, D., Stangl, J., Müller-Buschbaum, K. and Beuerle, F. (2016) Three-Dimensional Metal-Fullerene Frameworks, Chemistry - A European Journal, 22(17), pp. 5982-5987. https://doi.org/10.1002/chem.201505137

APA-Zitierstil: Kraft, A., Roth, P., Schmidt, D., Stangl, J., Müller-Buschbaum, K., & Beuerle, F. (2016). Three-Dimensional Metal-Fullerene Frameworks. Chemistry - A European Journal. 22(17), 5982-5987. https://doi.org/10.1002/chem.201505137