Journal article

Authors list: Zottnick, SH; Sprenger, JAP; Finze, M; Müller-Buschbaum, K

Publication year: 2018

Pages: 1445-1450

Journal: Journal of Inorganic and General Chemistry

Volume number: 644

Issue number: 22

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.201800254

Publisher: Wiley

Abstract: 
Starting from phthalic acid and Na[BH4], the low-melting salt [EMIm(+)][BPB] [EMIm(+) = 1-ethyl-3-methylimidazolium; BPB- = bis(phthalato)borate] was synthesized and further reacted with Tb(NO3)(3)center dot 6H(2)O to yield the one-dimensional coordination polymer (1)(infinity)[Tb(o-HBDC)(H2O)(6)][BPB](2). Product formation is a result of the formation of the ortho-phthalato mono acid (o-HBDC) from [BPB](-) anions in the process and leads to linkage of adjacent Tb3+ ions resulting in the cationic strand (1)(infinity)[Tb(o-HBDC)](2+). The cationic charge of the coordination polymer is compensated by the [BPB](-) anions in the crystal structure. Furthermore, the one-dimensional coordination polymer (1)(infinity)[Tb(o-HBDC)(H2O)(6)][BPB](2) shows characteristic luminescence based on the 4f-4f transitions of the Tb3+ ions upon excitation with UV light.

Harvard Citation style: Zottnick, S., Sprenger, J., Finze, M. and Müller-Buschbaum, K. (2018) Transformation of [EMIm][BPB] into a Cationic Luminescent Ln-Coordination Polymer with the Bis(phthalato)borate Anion, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 644(22), pp. 1445-1450. https://doi.org/10.1002/zaac.201800254

APA Citation style: Zottnick, S., Sprenger, J., Finze, M., & Müller-Buschbaum, K. (2018). Transformation of [EMIm][BPB] into a Cationic Luminescent Ln-Coordination Polymer with the Bis(phthalato)borate Anion. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 644(22), 1445-1450. https://doi.org/10.1002/zaac.201800254