Journalartikel

Autorenliste: Kohrs, D; Becker, J; Wegner, HA

Jahr der Veröffentlichung: 2022

Seiten: e202104239-

Zeitschrift: Chemistry - A European Journal

Bandnummer: 28

Heftnummer: 8

ISSN: 0947-6539

eISSN: 1521-3765

Open Access Status: Hybrid

DOI Link: https://doi.org/10.1002/chem.202104239

Verlag: Wiley

Abstract: 
Herein, we report a modular synthesis providing access to substituted cycloparaphenylenes (CPPs) of different sizes. A key synthon introducing two geminal ester units was efficiently prepared by [2+2+2] cycloaddition. This building block can be conveniently converted to macrocyclic precursors controlling the ring size of the final CPP. Efficient reductive aromatization through single-electron transfer provided the substituted nanohoops in a straightforward manner. The tBu ester substitution pattern enables a tube-like arrangement in the solid-state governed by van der Waals interactions that exhibits one of the tightest packings of CPPs in tube direction, thus opening new avenues in the crystal design of CPPs.

Harvard-Zitierstil: Kohrs, D., Becker, J. and Wegner, H. (2022) A Modular Synthesis of Substituted Cycloparaphenylenes, Chemistry - A European Journal, 28(8), Article e202104239. p. e202104239. https://doi.org/10.1002/chem.202104239

APA-Zitierstil: Kohrs, D., Becker, J., & Wegner, H. (2022). A Modular Synthesis of Substituted Cycloparaphenylenes. Chemistry - A European Journal. 28(8), Article e202104239, e202104239. https://doi.org/10.1002/chem.202104239