Journal article

Authors list: Stergiou, A; Rio, J; Griwatz, JH; Arčon, D; Wegner, HA; Ewels, CP; Tagmatarchis, N

Publication year: 2019

Pages: 17745-17750

Journal: Angewandte Chemie International Edition

Volume number: 58

Issue number: 49

ISSN: 1433-7851

eISSN: 1521-3773

Open access status: Hybrid

DOI Link: https://doi.org/10.1002/anie.201909126

Publisher: Wiley

Abstract: 
A major handicap towards the exploitation of radicals is their inherent instability. In the paramagnetic azafullerenyl radical C59N., the unpaired electron is strongly localized next to the nitrogen atom, which induces dimerization to diamagnetic bis(azafullerene), (C59N)(2). Conventional stabilization by introducing steric hindrance around the radical is inapplicable here because of the concave fullerene geometry. Instead, we developed an innovative radical shielding approach based on supramolecular complexation, exploiting the protection offered by a [10]cycloparaphenylene ([10]CPP) nanobelt encircling the C59N. radical. Photoinduced radical generation is increased by a factor of 300. The EPR signal showing characteristic N-14 hyperfine splitting of C59N.subset of [10]CPP was traced even after several weeks, which corresponds to a lifetime increase of >10(8). The proposed approach can be generalized by tuning the diameter of the employed nanobelts, opening new avenues for the design and exploitation of radical fullerenes.

Harvard Citation style: Stergiou, A., Rio, J., Griwatz, J., Arčon, D., Wegner, H., Ewels, C., et al. (2019) A Long-Lived Azafullerenyl Radical Stabilized by Supramolecular Shielding with a [10]Cycloparaphenylene, Angewandte Chemie International Edition, 58(49), pp. 17745-17750. https://doi.org/10.1002/anie.201909126

APA Citation style: Stergiou, A., Rio, J., Griwatz, J., Arčon, D., Wegner, H., Ewels, C., & Tagmatarchis, N. (2019). A Long-Lived Azafullerenyl Radical Stabilized by Supramolecular Shielding with a [10]Cycloparaphenylene. Angewandte Chemie International Edition. 58(49), 17745-17750. https://doi.org/10.1002/anie.201909126