Journal article

Authors list: Will, J; Schneider, L; Becker, J; Becker, S; Miska, A; Gawlig, C; Schindler, S

Publication year: 2020

Pages: 999-1003

Journal: Israel Journal of Chemistry

Volume number: 60

Issue number: 10-11

ISSN: 0021-2148

eISSN: 1869-5868

Open access status: Hybrid

DOI Link: https://doi.org/10.1002/ijch.201900120

Publisher: Wiley

Abstract: 
A new tripodal imine ligand tris(2-(propan-2-ylideneamino)ethyl)amine (imine(3)tren) was prepared in order to stabilize high valent iron-oxido complexes. Iron complexes were synthesized in template reactions from iron(II) salts, tris(2-aminoethyl)amine (tren) and acetone. Due to the reversibility of the imine formation, complexes with different ligands were obtained depending on the reaction conditions. Three complexes, [Fe(imine(3)tren)(OAc)(2)] (1), [Fe(imine(3)tren)(OAc)]OTf (2) and [(imine(3)tren)(2)Fe-2(F)(2)](SbF6)(2) (3), could be synthesized and structurally characterized. However, reactions with hydrogen peroxide, iodosobenzene or ozone did not lead to any kind of "oxygen adduct" complex that could be spectroscopically observed.

Harvard Citation style: Will, J., Schneider, L., Becker, J., Becker, S., Miska, A., Gawlig, C., et al. (2020) Synthesis and Reactivity of Iron(II) Complexes with a New Tripodal Imine Ligand, Israel Journal of Chemistry, 60(10-11), pp. 999-1003. https://doi.org/10.1002/ijch.201900120

APA Citation style: Will, J., Schneider, L., Becker, J., Becker, S., Miska, A., Gawlig, C., & Schindler, S. (2020). Synthesis and Reactivity of Iron(II) Complexes with a New Tripodal Imine Ligand. Israel Journal of Chemistry. 60(10-11), 999-1003. https://doi.org/10.1002/ijch.201900120