Journal article

Authors list: Schäfer, T; Sedykh, AE; Becker, J; Müller-Buschbaum, K

Publication year: 2020

Pages: 1555-1562

Journal: Journal of Inorganic and General Chemistry

Volume number: 646

Issue number: 18

ISSN: 0044-2313

eISSN: 1521-3749

Open access status: Hybrid

DOI Link: https://doi.org/10.1002/zaac.202000103

Publisher: Wiley

Abstract: 
Four isotypic one-dimensional coordination polymers (CP) were synthesized using the group 13 metal halides AlBr3, GaCl3, GaBr3, and InI3 and the tridentate ligand 2,4,6-tri(4-pyridyl)-1,3,5-triazine (tpt) serving as bidentate linker. The neutral one-dimensional CPs (1)(infinity)[AlBr3(tpt)], (1)(infinity)[GaCl3(tpt)], (1)(infinity)[GaBr3(tpt)], and (1)(infinity)[InI3(tpt)] are constituted by zigzag-shaped chains in the crystal structure, in which one coordination site of the tpt ligand remains uncoordinated. All CPs were characterized by SCXRD, PXRD, simultaneous DTA/TG, elemental-analysis and IR spectroscopy. Furthermore, three complexes of the composition [(AlBr3)(3)(tpt)], [(GaCl3)(3)(tpt)], and [(GaBr3)(3)(tpt)] were structurally characterized by SCXRD, being preliminary and side products of the formation of the coordination polymers.

Harvard Citation style: Schäfer, T., Sedykh, A., Becker, J. and Müller-Buschbaum, K. (2020) Group 13 Metal Halide Based Coordination Polymers of Al, Ga, In and 2,4,6-Tri(4-pyridyl)-1,3,5-triazine, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 646(18), pp. 1555-1562. https://doi.org/10.1002/zaac.202000103

APA Citation style: Schäfer, T., Sedykh, A., Becker, J., & Müller-Buschbaum, K. (2020). Group 13 Metal Halide Based Coordination Polymers of Al, Ga, In and 2,4,6-Tri(4-pyridyl)-1,3,5-triazine. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 646(18), 1555-1562. https://doi.org/10.1002/zaac.202000103