Journal article

Authors list: Sedykh, AE; Sotnik, SA; Kurth, DG; Volochnyuk, DM; Kolotilov, SV; Müller-Buschbaum, K

Publication year: 2020

Pages: 1710-1714

Journal: Journal of Inorganic and General Chemistry

Volume number: 646

Issue number: 20

ISSN: 0044-2313

eISSN: 1521-3749

DOI Link: https://doi.org/10.1002/zaac.201900319

Publisher: Wiley

Abstract: 
A dimeric complex of trivalent europium [Eu2Cl4(bc)(2)(ptpy)(2)] (1), containing the separate ligands 4'-phenyl-2,2':6',2''-terpyridine (ptpy) and benzoate (bc(-)) and a one-dimensional double strand coordination polymer of the composition(infinity)(1)[EuCl2(cptpy)] (2) with 4-[2,2':6',2''-terpyridin]-4'-yl-benzoate (cptpy(-)) were obtained. The products exhibit structural similarities despite the character of joint and separate functionality of the ligands. The dimer1shows photoluminescence with high quantum yield [61(2) %]. Eu(3+)emission lifetime is 1.493(1) ms at room temperature and rises to 1.649(1) ms upon cooling to 77 K.

Harvard Citation style: Sedykh, A., Sotnik, S., Kurth, D., Volochnyuk, D., Kolotilov, S. and Müller-Buschbaum, K. (2020) Similarities of Coordination Polymer and Dimeric Complex of Europium(III) with Joint and Separate Terpyridine and Benzoate, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 646(20), pp. 1710-1714. https://doi.org/10.1002/zaac.201900319

APA Citation style: Sedykh, A., Sotnik, S., Kurth, D., Volochnyuk, D., Kolotilov, S., & Müller-Buschbaum, K. (2020). Similarities of Coordination Polymer and Dimeric Complex of Europium(III) with Joint and Separate Terpyridine and Benzoate. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 646(20), 1710-1714. https://doi.org/10.1002/zaac.201900319