Journal article

Authors list: Sedykh, AE; Kurth, DG; Müller-Buschbaum, K

Publication year: 2021

Pages: 359-364

Journal: Journal of Inorganic and General Chemistry

Volume number: 647

Issue number: 4

ISSN: 0044-2313

eISSN: 1521-3749

Open access status: Hybrid

DOI Link: https://doi.org/10.1002/zaac.202000347

Publisher: Wiley

Abstract: 
A trivalent scandium complex with 4 '-phenyl-2,2 ':6 ',2 ''-terpyridine [ScCl3(ptpy)] has been synthesized and characterized. At low temperatures, [ScCl3(ptpy)] shows a luminescence afterglow of green color in the crystalline form and of cyan color in a glass matrix, caused by phosphorescence of long triplet state emission lifetime (1.63(2) s in a glass matrix, 0.56(3) s in the crystalline form). In addition, the complex is thermally remarkably stable up to 495 degrees C, especially in comparison with previously reported similar lanthanide and group 3 metal chloride complexes containing ptpy.

Harvard Citation style: Sedykh, A., Kurth, D. and Müller-Buschbaum, K. (2021) Phosphorescence Afterglow and Thermal Properties of [ScCl3(ptpy)] (ptpy: 4'-phenyl-2,2',6',2''-terpyridine), Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 647(4), pp. 359-364. https://doi.org/10.1002/zaac.202000347

APA Citation style: Sedykh, A., Kurth, D., & Müller-Buschbaum, K. (2021). Phosphorescence Afterglow and Thermal Properties of [ScCl3(ptpy)] (ptpy: 4'-phenyl-2,2',6',2''-terpyridine). Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 647(4), 359-364. https://doi.org/10.1002/zaac.202000347