Matrix isolation and photorearrangement of cis- and trans-1,2-ethenediol to glycolaldehyde - Forschungsportal der Justus-Liebig-Universität Gießen:

Journalartikel

Matrix isolation and photorearrangement of cis- and trans-1,2-ethenediol to glycolaldehyde

Autorenliste: Mardyukov, A; Wende, RC; Schreiner, PR

Jahr der Veröffentlichung: 2023

Seiten: 2596-2599

Zeitschrift: Chemical Communications

Bandnummer: 59

Heftnummer: 18

ISSN: 1359-7345

eISSN: 1364-548X

Open Access Status: Green

DOI Link: https://doi.org/10.1039/d2cc06331j

Verlag: Royal Society of Chemistry

Abstract:
1,2-Ethenediols are deemed key intermediates in prebiotic and interstellar syntheses of carbohydrates. Here we present the gas-phase synthesis of these enediols, the high-energy tautomers of glycolaldehyde, trapped in cryogenic argon matrices. Importantly, upon photolysis at lambda = 180-254 nm, the enols rearrange to the simplest sugar glycolaldehyde.

Autoren/Herausgeber

- Uni.-Prof. Dr. Peter Richard Schreiner, PhD

Zitierstile

Harvard-Zitierstil: Mardyukov, A., Wende, R. and Schreiner, P. (2023) Matrix isolation and photorearrangement of cis- and trans-1,2-ethenediol to glycolaldehyde, Chemical Communications, 59(18), pp. 2596-2599. https://doi.org/10.1039/d2cc06331j

APA-Zitierstil: Mardyukov, A., Wende, R., & Schreiner, P. (2023). Matrix isolation and photorearrangement of cis- and trans-1,2-ethenediol to glycolaldehyde. Chemical Communications. 59(18), 2596-2599. https://doi.org/10.1039/d2cc06331j