Journalartikel

Autorenliste: Rösel, S; Balestrieri, C; Schreiner, PR

Jahr der Veröffentlichung: 2017

Seiten: 405-410

Zeitschrift: Chemical Science

Bandnummer: 8

Heftnummer: 1

Open Access Status: Gold

DOI Link: https://doi.org/10.1039/C6SC02727J

Verlag: Royal Society of Chemistry

Abstract: 

The structure and dynamics of enigmatic hexa(3,5-di-tert-butylphenyl) ethane was characterized via NMR spectroscopy for the first time. Our variable temperature NMR analysis demonstrates an enthalpyentropy compensation that results in a vanishingly low dissociation energy (Delta G(d)(298) = -1.60(6) kcal mol(-1)). An in silico study of increasingly larger all-meta alkyl substituted hexaphenylethane derivatives (Me, Pr-i, Bu-t, Cy, 1-Ad) reveals a non-intuitive correlation between increased dimer stability with increasing steric crowding. This stabilization originates from London dispersion as expressed through the increasing polarizability of the alkyl substituents. Substitution with conformationally flexible hydrocarbon moieties, e. g., cyclohexyl, introduces large unfavourable entropy contributions. Therefore, using rigid alkyl groups like tertbutyl or adamantyl as dispersion energy donors (DED) is essential to help stabilize extraordinary bonding situations.

Harvard-Zitierstil: Rösel, S., Balestrieri, C. and Schreiner, P. (2017) Sizing the role of London dispersion in the dissociation of all-meta tert-butyl hexaphenylethane, Chemical Science, 8(1), pp. 405-410. https://doi.org/10.1039/C6SC02727J

APA-Zitierstil: Rösel, S., Balestrieri, C., & Schreiner, P. (2017). Sizing the role of London dispersion in the dissociation of all-meta tert-butyl hexaphenylethane. Chemical Science. 8(1), 405-410. https://doi.org/10.1039/C6SC02727J