Journalartikel

Autorenliste: Miska, A; Schurr, D; Rinke, G; Dittmeyer, R; Schindler, S

Jahr der Veröffentlichung: 2018

Seiten: 459-465

Zeitschrift: Chemical Engineering Science

Bandnummer: 190

ISSN: 0009-2509

DOI Link: https://doi.org/10.1016/j.ces.2018.05.064

Verlag: Elsevier

Abstract: 
It was demonstrated previously that a system consisting of a dinuclear iron complex with the ligand HPTB (N,N,N',N'-tetrakis[2-benzimidazolylmethyl]-1,3-diamino-2-propanol) reacts with dioxygen to form a peroxido complex that may be used for the oxidation of organic substrates. Detailed kinetic studies using stopped-flow techniques and a SuperFocus mixer clearly demonstrate that this complex has a high potential for future applications in catalytic selective oxidation processes in industry. Especially for that reason a reaction KIT system for easy handling was developed that allows to start with a stable iron (III) complex that is reduced (activated) prior to its oxidation with dioxygen.This work has been selected by the Editors as a Featured Cover Article for this issue. (C) 2018 Elsevier Ltd. All rights reserved.

Harvard-Zitierstil: Miska, A., Schurr, D., Rinke, G., Dittmeyer, R. and Schindler, S. (2018) From model compounds to applications: Kinetic studies on the activation of dioxygen using an iron complex in a SuperFocus mixer, Chemical Engineering Science, 190, pp. 459-465. https://doi.org/10.1016/j.ces.2018.05.064

APA-Zitierstil: Miska, A., Schurr, D., Rinke, G., Dittmeyer, R., & Schindler, S. (2018). From model compounds to applications: Kinetic studies on the activation of dioxygen using an iron complex in a SuperFocus mixer. Chemical Engineering Science. 190, 459-465. https://doi.org/10.1016/j.ces.2018.05.064