Journal article

From model compounds to applications: Kinetic studies on the activation of dioxygen using an iron complex in a SuperFocus mixer


Authors listMiska, A; Schurr, D; Rinke, G; Dittmeyer, R; Schindler, S

Publication year2018

Pages459-465

JournalChemical Engineering Science

Volume number190

ISSN0009-2509

DOI Linkhttps://doi.org/10.1016/j.ces.2018.05.064

PublisherElsevier


Abstract
It was demonstrated previously that a system consisting of a dinuclear iron complex with the ligand HPTB (N,N,N',N'-tetrakis[2-benzimidazolylmethyl]-1,3-diamino-2-propanol) reacts with dioxygen to form a peroxido complex that may be used for the oxidation of organic substrates. Detailed kinetic studies using stopped-flow techniques and a SuperFocus mixer clearly demonstrate that this complex has a high potential for future applications in catalytic selective oxidation processes in industry. Especially for that reason a reaction KIT system for easy handling was developed that allows to start with a stable iron (III) complex that is reduced (activated) prior to its oxidation with dioxygen.This work has been selected by the Editors as a Featured Cover Article for this issue. (C) 2018 Elsevier Ltd. All rights reserved.



Citation Styles

Harvard Citation styleMiska, A., Schurr, D., Rinke, G., Dittmeyer, R. and Schindler, S. (2018) From model compounds to applications: Kinetic studies on the activation of dioxygen using an iron complex in a SuperFocus mixer, Chemical Engineering Science, 190, pp. 459-465. https://doi.org/10.1016/j.ces.2018.05.064

APA Citation styleMiska, A., Schurr, D., Rinke, G., Dittmeyer, R., & Schindler, S. (2018). From model compounds to applications: Kinetic studies on the activation of dioxygen using an iron complex in a SuperFocus mixer. Chemical Engineering Science. 190, 459-465. https://doi.org/10.1016/j.ces.2018.05.064


Last updated on 2025-21-05 at 13:25