Journalartikel

Autorenliste: Tordin, E; List, M; Monkowius, U; Schindler, S; Knör, G

Jahr der Veröffentlichung: 2013

Seiten: 90-96

Zeitschrift: Inorganica Chimica Acta

Bandnummer: 402

ISSN: 0020-1693

Open Access Status: Hybrid

DOI Link: https://doi.org/10.1016/j.ica.2013.03.034

Verlag: Elsevier

Abstract: 
Four new compounds of the general formula [M(L)(CH₃COO)][PF₆],
where L is a tetradentate tripodal ligand such as
tris[2-(dimethylamino)ethyl]amine (L1) or
(2-aminoethyl)bis(2-pyridylmethyl)amine (L2) and M is Co(II), Ni(II) or
Cu(II), have been prepared employing a simple two-step synthesis. The
compounds have been characterised by elemental analysis, mass
spectroscopy, IR spectroscopy and X-ray diffraction. The catalytic
properties of the derivatives containing the aliphatic ligand L1 have
been investigated in particular toward the oxidation of cyclohexane and
adamantane in the presence of the sacrificial oxidant m-CPBA (meta-chloroperbenzoic acid). Good TONs and selectivity have been determined for the cobalt and nickel compounds.

Harvard-Zitierstil: Tordin, E., List, M., Monkowius, U., Schindler, S. and Knör, G. (2013) Synthesis and characterisation of cobalt, nickel and copper complexes with tripodal 4N ligands as novel catalysts for the homogeneous partial oxidation of alkanes, Inorganica Chimica Acta, 402, pp. 90-96. https://doi.org/10.1016/j.ica.2013.03.034

APA-Zitierstil: Tordin, E., List, M., Monkowius, U., Schindler, S., & Knör, G. (2013). Synthesis and characterisation of cobalt, nickel and copper complexes with tripodal 4N ligands as novel catalysts for the homogeneous partial oxidation of alkanes. Inorganica Chimica Acta. 402, 90-96. https://doi.org/10.1016/j.ica.2013.03.034