Journal article

Authors list: Tordin, E; List, M; Monkowius, U; Schindler, S; Knör, G

Publication year: 2013

Pages: 90-96

Journal: Inorganica Chimica Acta

Volume number: 402

ISSN: 0020-1693

Open access status: Hybrid

DOI Link: https://doi.org/10.1016/j.ica.2013.03.034

Publisher: Elsevier

Abstract: 
Four new compounds of the general formula [M(L)(CH₃COO)][PF₆],
where L is a tetradentate tripodal ligand such as
tris[2-(dimethylamino)ethyl]amine (L1) or
(2-aminoethyl)bis(2-pyridylmethyl)amine (L2) and M is Co(II), Ni(II) or
Cu(II), have been prepared employing a simple two-step synthesis. The
compounds have been characterised by elemental analysis, mass
spectroscopy, IR spectroscopy and X-ray diffraction. The catalytic
properties of the derivatives containing the aliphatic ligand L1 have
been investigated in particular toward the oxidation of cyclohexane and
adamantane in the presence of the sacrificial oxidant m-CPBA (meta-chloroperbenzoic acid). Good TONs and selectivity have been determined for the cobalt and nickel compounds.

Harvard Citation style: Tordin, E., List, M., Monkowius, U., Schindler, S. and Knör, G. (2013) Synthesis and characterisation of cobalt, nickel and copper complexes with tripodal 4N ligands as novel catalysts for the homogeneous partial oxidation of alkanes, Inorganica Chimica Acta, 402, pp. 90-96. https://doi.org/10.1016/j.ica.2013.03.034

APA Citation style: Tordin, E., List, M., Monkowius, U., Schindler, S., & Knör, G. (2013). Synthesis and characterisation of cobalt, nickel and copper complexes with tripodal 4N ligands as novel catalysts for the homogeneous partial oxidation of alkanes. Inorganica Chimica Acta. 402, 90-96. https://doi.org/10.1016/j.ica.2013.03.034