Journalartikel

Iron(III) complexes with the ligand N ',N '-bis[(2-pyridyl)methyl]ethylenediamine (uns-penp) and its amide derivative N-acetyl-N ',N '-bis[(2-pyridyl)methyl]ethylenediamine (acetyl-uns-penp)


AutorenlisteXu, JY; Astner, J; Walter, O; Heinemann, FW; Schindler, S; Merkel, M; Krebs, B

Jahr der Veröffentlichung2006

Seiten1601-1610

ZeitschriftEuropean Journal of Inorganic Chemistry

Bandnummer2006

Heftnummer8

ISSN1434-1948

DOI Linkhttps://doi.org/10.1002/ejic.200500902

VerlagWiley-VCH Verlag


Abstract
Synthesis and structural characterization of the iron(III) complexes of the tripodal ligands N',N'-bis[(2-pyridyl)methyl]ethylenediamine (uns-penp), [Fe(uns-penp)Cl-2]ClO4CH3CN, [{Fe(uns-penp)Cl}(2)O](ClO4)(2)center dot 2CH(3)CN and the amide derivative N-Acetyl-N',N'-bis[(2-pyridyl)methyl]ethylenediamine (acetyl-uns-penp), [Fe-2(acetyl-uns-penp)(2)O]-(ClO4)(2)center dot H2O, [Fe(acetyl-uns-penp)(tcc)Br]center dot(C2H5)(2)O (tcc = tetra chlorocatecholate), and [{(Fe(acetyl-uns-penp)(tcc)}(2)O]center dot(C2H5)(2)O center dot CH3OH are reported. Catechol dioxygenase reactivity of in situ prepared complex solutions was tested and showed that all complexes reacted slower compared with the iron tmpa system described in the literature.



Zitierstile

Harvard-ZitierstilXu, J., Astner, J., Walter, O., Heinemann, F., Schindler, S., Merkel, M., et al. (2006) Iron(III) complexes with the ligand N ',N '-bis[(2-pyridyl)methyl]ethylenediamine (uns-penp) and its amide derivative N-acetyl-N ',N '-bis[(2-pyridyl)methyl]ethylenediamine (acetyl-uns-penp), European Journal of Inorganic Chemistry, 2006(8), pp. 1601-1610. https://doi.org/10.1002/ejic.200500902

APA-ZitierstilXu, J., Astner, J., Walter, O., Heinemann, F., Schindler, S., Merkel, M., & Krebs, B. (2006). Iron(III) complexes with the ligand N ',N '-bis[(2-pyridyl)methyl]ethylenediamine (uns-penp) and its amide derivative N-acetyl-N ',N '-bis[(2-pyridyl)methyl]ethylenediamine (acetyl-uns-penp). European Journal of Inorganic Chemistry. 2006(8), 1601-1610. https://doi.org/10.1002/ejic.200500902



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