Journal article

Authors list: Xu, JY; Astner, J; Walter, O; Heinemann, FW; Schindler, S; Merkel, M; Krebs, B

Publication year: 2006

Pages: 1601-1610

Journal: European Journal of Inorganic Chemistry

Volume number: 2006

Issue number: 8

ISSN: 1434-1948

DOI Link: https://doi.org/10.1002/ejic.200500902

Publisher: Wiley-VCH Verlag

Abstract: 
Synthesis and structural characterization of the iron(III) complexes of the tripodal ligands N',N'-bis[(2-pyridyl)methyl]ethylenediamine (uns-penp), [Fe(uns-penp)Cl-2]ClO4CH3CN, [{Fe(uns-penp)Cl}(2)O](ClO4)(2)center dot 2CH(3)CN and the amide derivative N-Acetyl-N',N'-bis[(2-pyridyl)methyl]ethylenediamine (acetyl-uns-penp), [Fe-2(acetyl-uns-penp)(2)O]-(ClO4)(2)center dot H2O, [Fe(acetyl-uns-penp)(tcc)Br]center dot(C2H5)(2)O (tcc = tetra chlorocatecholate), and [{(Fe(acetyl-uns-penp)(tcc)}(2)O]center dot(C2H5)(2)O center dot CH3OH are reported. Catechol dioxygenase reactivity of in situ prepared complex solutions was tested and showed that all complexes reacted slower compared with the iron tmpa system described in the literature.

Harvard Citation style: Xu, J., Astner, J., Walter, O., Heinemann, F., Schindler, S., Merkel, M., et al. (2006) Iron(III) complexes with the ligand N ',N '-bis[(2-pyridyl)methyl]ethylenediamine (uns-penp) and its amide derivative N-acetyl-N ',N '-bis[(2-pyridyl)methyl]ethylenediamine (acetyl-uns-penp), European Journal of Inorganic Chemistry, 2006(8), pp. 1601-1610. https://doi.org/10.1002/ejic.200500902

APA Citation style: Xu, J., Astner, J., Walter, O., Heinemann, F., Schindler, S., Merkel, M., & Krebs, B. (2006). Iron(III) complexes with the ligand N ',N '-bis[(2-pyridyl)methyl]ethylenediamine (uns-penp) and its amide derivative N-acetyl-N ',N '-bis[(2-pyridyl)methyl]ethylenediamine (acetyl-uns-penp). European Journal of Inorganic Chemistry. 2006(8), 1601-1610. https://doi.org/10.1002/ejic.200500902