Journalartikel

Observation of a Transient Structural Change during the Reversible Reduction of a Porphyrin Thin‐Film Electrode


AutorenlisteJaeger, NI; Lehmkuhl, R; Schlettwein, D; Wöhrle, D

Jahr der Veröffentlichung1994

Seiten1735-1739

ZeitschriftJournal of The Electrochemical Society

Bandnummer141

Heftnummer7

ISSN0013-4651

DOI Linkhttps://doi.org/10.1149/1.2054996

VerlagThe Electrochemical Society


Abstract
Cyclic voltammetry has been performed on thin films of tetrapyrazinotetraazaporphyrinatocopper(II) (1) on either gold or ITO in contact with acidic electrolytes. The films show a reversible electrochromic behavior with one cathodic and two anodic peaks. The two separate reoxidation waves in the cyclic voltammogram are interpreted by an intermediate compound formed during the reoxidation process. The kinetics of the formation and the nature of the intermediate are elucidated from the cyclic voltammograms and from spectroelectrochemical experiments.



Autoren/Herausgeber




Zitierstile

Harvard-ZitierstilJaeger, N., Lehmkuhl, R., Schlettwein, D. and Wöhrle, D. (1994) Observation of a Transient Structural Change during the Reversible Reduction of a Porphyrin Thin‐Film Electrode, Journal of The Electrochemical Society, 141(7), pp. 1735-1739. https://doi.org/10.1149/1.2054996

APA-ZitierstilJaeger, N., Lehmkuhl, R., Schlettwein, D., & Wöhrle, D. (1994). Observation of a Transient Structural Change during the Reversible Reduction of a Porphyrin Thin‐Film Electrode. Journal of The Electrochemical Society. 141(7), 1735-1739. https://doi.org/10.1149/1.2054996


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