Two New Benzoate‐di(methylcyclopentadienyl)ytterbium(III) Complexes: [Yb(MeCp)2(O2CC6F5)]2 and [Yb(MeCp)2(O2C‐o‐HC6F4)]2 - Forschungsportal der Justus-Liebig-Universität Gießen:

Journalartikel

Two New Benzoate‐di(methylcyclopentadienyl)ytterbium(III) Complexes: [Yb(MeCp)2(O2CC6F5)]2 and [Yb(MeCp)2(O2C‐o‐HC6F4)]2

Autorenliste: Deacon, GB; Quitmann, CC; Müller-Buschbaum, K; Meyer, G

Jahr der Veröffentlichung: 2003

Seiten: 589-591

Zeitschrift: Journal of Inorganic and General Chemistry

Bandnummer: 629

Heftnummer: 4

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.200390098

Verlag: Wiley

Abstract:
Transparent orange crystals of [Yb(MeCp)2(O2CC6F5)]2 and [Yb(MeCp)2(O2C‐o‐HC6F4)]2 were obtained by oxidation of Yb(MeCp)2 with M(O2CR) (M = 1/2 Hg, Tl; R = C6F5, o‐HC6F4) in tetrahydrofuran. They have a dimeric structure with bridging bidentate (O, O')‐benzoate groups and eight coordinated ytterbium. Both crystallise isotypic in the orthorhombic space group Pbca. Room temperature as well as low temperature single crystal X‐ray investigations show the o‐H/F positions in [Yb(MeCp)2(O2C‐o‐HC6F4)]2 not to be ordered.

Autoren/Herausgeber

- Uni.-Prof. Dr. Klaus Müller-Buschbaum

Zitierstile

Harvard-Zitierstil: Deacon, G., Quitmann, C., Müller-Buschbaum, K. and Meyer, G. (2003) Two New Benzoate‐di(methylcyclopentadienyl)ytterbium(III) Complexes: [Yb(MeCp)2(O2CC6F5)]2 and [Yb(MeCp)2(O2C‐o‐HC6F4)]2, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 629(4), pp. 589-591. https://doi.org/10.1002/zaac.200390098

APA-Zitierstil: Deacon, G., Quitmann, C., Müller-Buschbaum, K., & Meyer, G. (2003). Two New Benzoate‐di(methylcyclopentadienyl)ytterbium(III) Complexes: [Yb(MeCp)2(O2CC6F5)]2 and [Yb(MeCp)2(O2C‐o‐HC6F4)]2. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 629(4), 589-591. https://doi.org/10.1002/zaac.200390098