Two New Benzoate‐di(methylcyclopentadienyl)ytterbium(III) Complexes: [Yb(MeCp)2(O2CC6F5)]2 and [Yb(MeCp)2(O2C‐o‐HC6F4)]2 - Research portal of Justus Liebig University Giessen:

Journal article

Two New Benzoate‐di(methylcyclopentadienyl)ytterbium(III) Complexes: [Yb(MeCp)2(O2CC6F5)]2 and [Yb(MeCp)2(O2C‐o‐HC6F4)]2

Authors list: Deacon, GB; Quitmann, CC; Müller-Buschbaum, K; Meyer, G

Publication year: 2003

Pages: 589-591

Journal: Journal of Inorganic and General Chemistry

Volume number: 629

Issue number: 4

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.200390098

Publisher: Wiley

Abstract:
Transparent orange crystals of [Yb(MeCp)2(O2CC6F5)]2 and [Yb(MeCp)2(O2C‐o‐HC6F4)]2 were obtained by oxidation of Yb(MeCp)2 with M(O2CR) (M = 1/2 Hg, Tl; R = C6F5, o‐HC6F4) in tetrahydrofuran. They have a dimeric structure with bridging bidentate (O, O')‐benzoate groups and eight coordinated ytterbium. Both crystallise isotypic in the orthorhombic space group Pbca. Room temperature as well as low temperature single crystal X‐ray investigations show the o‐H/F positions in [Yb(MeCp)2(O2C‐o‐HC6F4)]2 not to be ordered.

Authors/Editors

- Uni.-Prof. Dr. Klaus Müller-Buschbaum

Citation Styles

Harvard Citation style: Deacon, G., Quitmann, C., Müller-Buschbaum, K. and Meyer, G. (2003) Two New Benzoate‐di(methylcyclopentadienyl)ytterbium(III) Complexes: [Yb(MeCp)2(O2CC6F5)]2 and [Yb(MeCp)2(O2C‐o‐HC6F4)]2, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 629(4), pp. 589-591. https://doi.org/10.1002/zaac.200390098

APA Citation style: Deacon, G., Quitmann, C., Müller-Buschbaum, K., & Meyer, G. (2003). Two New Benzoate‐di(methylcyclopentadienyl)ytterbium(III) Complexes: [Yb(MeCp)2(O2CC6F5)]2 and [Yb(MeCp)2(O2C‐o‐HC6F4)]2. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 629(4), 589-591. https://doi.org/10.1002/zaac.200390098